Articles such as safety laminates and solar cell modules containing high melt flow acid copolymer compositions

ABSTRACT

A polymeric film or sheet comprising an acid copolymer composition comprising acid copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the acid copolymer composition, wherein the acid copolymer has a Melt Index of about 75 to about 600 g/10 min. The acid copolymer composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims priority to U.S. Provisional Appin. No.60/901510, filed on Feb. 15, 2007, which is incorporated herein byreference in its entirety.

FIELD OF THE INVENTION

The invention relates to polymeric films or sheets comprising acidcopolymer compositions, and their use in articles such as safetylaminates and solar cell modules.

BACKGROUND OF THE INVENTION

Glass laminated products have contributed to society for almost acentury. Beyond the well known, every day automotive safety glass usedin windshields, laminated glass is used in all forms of thetransportation industry. Safety glass is characterized by high impactand penetration resistance and does not scatter glass shards and debriswhen shattered.

Safety glass typically consists of a sandwich of two glass sheets orpanels bonded together with an interlayer of a polymeric sheet. One orboth of the glass sheets may be replaced with optically clear rigidpolymeric sheets, such as sheets made of polycarbonates. Safety glasshas further evolved to include multiple layers of glass and polymericsheets bonded together with interlayers of polymeric sheets.

The interlayers used in safety glass are typically made from relativelythick polymer sheets, which exhibit toughness and bondability to theglass in the event of a crack or crash. Widely used interlayer materialsinclude complex, multicomponent compositions based on poly(vinylbutyral) (PVB), poly(urethane) (PU), poly(ethylene vinyl acetate) (EVA),acid copolymers and ionomers derived therefrom, and the like.

As a renewable energy resource, the use of solar cell modules is rapidlyexpanding. One preferred way of manufacturing a solar cell moduleinvolves forming a pre-laminate assembly comprising at least 5structural layers. The solar cell pre-laminates are constructed in thefollowing order starting from the top, or incident layer (that is, thelayer first contacted by light) and continuing to the backing (the layerfurthest removed from the incident layer): (1) incident layer (typicallya glass plate or a thin polymeric film (such as a fluoropolymer orpolyester film), but could conceivably be any material that istransparent to sunlight), (2) front encapsulant layer, (3)voltage-generating component (or solar cell component), (4) backencapsulant layer, and (5) backing layer.

The encapsulant layers are designed to encapsulate and protect thefragile voltage-generating component. Generally, a solar cellpre-laminate will incorporate at least two encapsulant layers sandwichedaround the solar cell component. The optical properties of the frontencapsulant layer must be such that light can be effectively transmittedto the solar cell component. Additionally, encapsulant layers generallyhave similar requirements and compositions to that described above forglazing interlayers.

The use of acid copolymer compositions as solar cell encapsulant filmsand sheets has been known within the art (see, e.g., U.S. Pat. No.3,957,537; U.S. Pat. No. 6,187,448; U.S. Pat. No. 6,320,116; U.S. Pat.No. 6,414,236; U.S. Pat. No. 6,586,271; U.S. Pat. No. 6,693,237; JP2000186114; JP 2001089616; JP 2001119047; JP 2001119056; JP 2001119057;JP 2001144313; JP 2001261904; JP 2004031445; JP 2004058583; JP2006032308; JP 2006036875; and JP 2006190867). For example, U.S. Pat.No. 6,187,448 and U.S. Pat. No. 6,320,116 disclose a multilayer solarcell encapsulant sheet that includes an acid copolymer layer. U.S. Pat.No. 6,414,236; U.S. Pat. No. 6,693,237 and JP 2006036875 disclose acidcopolymer compositions containing organic peroxides and silane couplingagents as solar cell encapsulant sheet materials. JP 2000186114discloses acid copolymer compositions, ionomeric compositions, andblends thereof as solar cell encapsulant sheets. JP 2001144313, JP2004031445, JP 2004058583, JP 2006032308 and JP 2006190867 disclose acidcopolymer compositions containing silane coupling agents as solar cellencapsulant sheet materials.

However, the acid copolymer resins being used in the art of solar cellmodules generally have a low melt flow index (MI) of 25 g/10 min orless. The use of such low melt flow acid copolymer resins requireshigher lamination temperatures (i.e., 130° C.-170° C.) and therefore maycomplicate the lamination process.

There is a need for polymeric film or sheet suitable for use asinterlayers in glass laminate end-use applications, such as safetywindows and solar cells, which do not have the shortcomings describedabove, as well as for compositions useful in forming such films orsheets. For instance, there is a desire to prepare useful compositionswith a reduced extrusion compounding temperature. For instance, there isa desire to reduce the lamination temperature, preferably to about 100°C. to about 120° C., or to reduce the lamination cycle time, or both,and therefore simplifying the lamination process. In addition, there isa desire for films or sheets that have enhanced adhesion strength underwide variety of lamination temperatures, including such desirable lowertemperatures, and to provide the laminates with improved shockresistance.

SUMMARY OF THE INVENTION

The invention is directed to a polymeric film or sheet comprising anacid copolymer composition comprising an acid copolymer of an alphaolefin and about 1 to about 30 wt % of alpha,beta-ethylenicallyunsaturated carboxylic acid having 3 to 8 carbons, based on the totalweight of the acid copolymer, wherein the acid copolymer has a MeltIndex of about 75 to about 600 g/10 min.

Preferably the acid copolymer has a Melt Index of about 100 to about 400g/10 min.

Preferably the alpha olefin is ethylene.

Preferably the alpha,beta-ethylenically unsaturated carboxylic acid isselected from the group consisting of acrylic acid, methacrylic acid,itaconic acid, maleic acid, maleic anhydride, fumaric acid, monomethylmaleic acid, and mixtures thereof.

Preferably the ionomeric copolymer comprises about 10 to about 25 wt %(more preferably about 15 to about 23 wt %, and most preferably about 18to about 23 wt %) of the alpha,beta-ethylenically unsaturated carboxylicacid.

The films or sheets of the invention preferably have a total thicknessof about 0.1 mil (0.003 mm) to about 250 mils (6.35 mm). In oneembodiment, the polymeric film or sheet preferably has a thickness ofabout 10 to about 250 mils (about 0.25 to about 6.35 mm). In anotherembodiment, the polymeric film or sheet preferably has a thickness ofabout 0.1 to about 10 mils (about 0.003 to about 0.25 mm). In a thirdembodiment, the thicknesthickness is preferably about 10 to about 20mils (about 0.25 to about 0.51 mm).

Preferably the acid copolymer composition further comprises an additiveselected from the group consisting of silane coupling agent, organicperoxide, and combinations thereof.

In one preferred embodiment, the acid copolymer composition containsabout 0.01 to about 5 wt % (more preferably about 0.05 to about 1 wt %)of the silane coupling agent, based on the total weight of the acidcopolymer composition. Preferably the silane coupling agent is selectedfrom the group consisting of gamma-chloropropylmethoxysilane,vinyltrimethoxysilane, vinyltriethoxysilane,vinyltris(beta-methoxyethoxy)silane,gamma-vinylbenzylpropyltrimethoxysilane,N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,gamma-methacryloxypropyltrimethoxysilane, vinyltriacetoxysilane,gamma-glycidoxypropyltrimethoxysilane,gamma-glycidoxypropyltriethoxysilane,beta-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, vinyltrichlorosilane,gamma-mercaptopropylmethoxysilane, gamma-aminopropyltriethoxysilane,N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, and mixturesthereof.

In another preferred embodiment, the acid copolymer composition containsabout 0.01 to about 10 wt % (preferably about 0.5 to about 3 wt %) ofthe organic peroxide, based on the total weight of the acid copolymercomposition. Preferably the organic peroxide is selected from the groupconsisting of 2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(tert-betylperoxy)hexane-3, di-tert-butyl peroxide,tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane,dicumyl peroxide, alpha, alpha′-bis(tert-butyl-peroxyisopropyl)benzene,n-butyl-4,4-bis(tert-butylperoxy)valerate,2,2-bis(tert-butylperoxy)butane, 1,1-bis(tert-butyl-peroxy)cyclohexane,1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane, tert-butylperoxybenzoate, benzoyl peroxide and mixtures thereof.

The invention is also directed to an article comprising an interlayerformed of the polymeric film or sheet and an additional layer selectedfrom the group consisting of glass, other polymeric interlayer sheets,polymeric film layers, and metal films or sheets.

By “other polymeric interlayer sheets” reference is made to aninterlayer sheet that may be the same as or different than interlayerformed of the polymeric film or sheet. Preferably the other polymericinterlayer sheets are formed of materials selected from the groupconsisting of acid copolymers and ionomers derived therefrom,poly(ethylene-co-vinyl acetate) (EVA), poly(vinyl acetal), polyurethane(PU), polyvinylchloride (PVC), polyethylenes, polyolefin blockelastomers, ethylene acrylate ester copolymers, silicone elastomers andepoxy resins. In one preferred embodiment, the other polymericinterlayer sheet is the same or substantially similar to the interlayerformed of the polymeric film or sheet.

Preferably the polymeric film layers are formed of materials selectedfrom the group consisting of polyesters, poly(ethylene naphthalate),polycarbonate, polyolefins, norbornene polymers, polystyrene,styrene-acrylate copolymers, acrylonitrile-styrene copolymers,polysulfones, nylons, poly(urethanes), acrylics, cellulose acetates,cellophane, vinyl chloride polymers, and fluoropolymers.

In a preferred embodiment, the article is a safety glass laminatewherein the additional layer is a glass sheet and the interlayer islaminated to the glass sheet. Preferably the interlayer is self-adheredto the glass sheets. Preferably the safety glass laminate comprises twosheets of glass and the interlayer is laminated between the glasssheets. Preferably the interlayer is self-adhered to the two glasssheets. Preferably the interlayer has a thickness of about 10 to about250 mils (about 0.25 to about 6.35 mm).

In another preferred embodiment, the article is a solar cellpre-laminate assembly and comprises a solar cell component comprisingone or a plurality of solar cells. The solar cell pre-laminate assemblypreferably further comprises a second polymeric layer that is positionednext to the solar cell component on the opposite side from the polymericfilm or sheet, wherein the second polymeric layer comprises a polymericcomposition selected from the group consisting of poly(vinyl acetal),ethylene vinyl acetate, polyurethane, polyvinylchloride, polyethylenes,polyolefin block elastomers, ethylene acrylate ester copolymers,copolymer of alpha olefin and alpha,beta-ethylenically unsaturatedcarboxylic acid and ionomers thereof, silicone elastomers and epoxyresins. The solar cell pre-laminate assembly preferably an incidentlayer that is formed of a transparent material (preferably glass or aplastic film or sheet, most preferably glass) and serves as an outerlayer at the light-receiving side of the assembly.

The solar cell pre-laminate assembly preferably comprises a backinglayer that serves as an outer layer at the back side of the assembly,wherein the backing layer preferably is formed of glass, plastic filmsor sheets, or metal films or sheets.

In one preferred embodiment, the solar cell pre-laminate assemblyconsists essentially of, from top to bottom, (i) an incident layerformed of a transparent material, which is positioned next to, (ii) afront encapsulant layer that is positioned next to, (iii) a solar cellcomponent comprising one or a plurality of solar cells, which ispositioned next to, (iv) an optional back encapsulant layer that ispositioned next to, (v) a backing layer, wherein at least one of theencapsulant layers is formed of the polymeric film or sheet.

The invention is further directed to an article which is a solar cellprepared by the steps comprising (a) providing interlayer formed of thepolymeric film or sheet, (b) providing a solar cell component comprisingone or a plurality of solar cells; and (c) encapsulating the solar cellcomponent in a matrix comprising the acid copolymer composition. Theinvention is also directed to a process of manufacturing an article,wherein the article is a solar cell module, the process comprising: (i)providing a solar cell pre-laminate assembly, and (ii) laminating thepre-laminate assembly to form the solar cell module. Preferably the stepof lamination is conducted by subjecting the assembly to heat and,optionally, vacuum.

The invention is also directed to an improved polymeric compositioncomprising an acid copolymer composition and an additive, wherein (i)the acid copolymer composition comprises a copolymer of an alpha olefinand about 1 to about 30 wt % of an alpha,beta-ethylenically unsaturatedcarboxylic acid having 3 to 8 carbons, based on the total weight of theacid copolymer, (ii) the acid copolymer has a Melt Index of about 75 toabout 600 g/10 min and (iii) the additive is selected from the groupconsisting of silane coupling agent, organic peroxide, and combinationsthereof. The invention is also directed to shaped articles comprisingthis polymeric composition. Preferably the shaped article is a polymericfilm or sheet. Preferably the film or sheet is a multilayer film orsheet comprising one surface layer formed of the polymeric composition.Preferably the multilayer film or sheet comprises two surface layerswith both being formed of the polymeric composition. One preferredembodiment is a solar cell or solar cell pre-laminate.

DETAILED DESCRIPTION OF THE INVENTION

All publications, patent applications, patents, and other documentsmentioned herein are incorporated by reference in their entirety. Unlessotherwise defined, all technical and scientific terms used herein havethe same meaning as commonly understood by one of ordinary skill in theart to which this invention belongs. In case of conflict, the presentspecification, including definitions, will control.

Although methods and materials similar or equivalent to those describedherein can be used in the practice or testing of the invention, suitablemethods and materials are described herein.

Unless stated otherwise, all percentages, parts, ratios, etc., are byweight.

When an amount, concentration, or other value or parameter is given aseither a range, preferred range or a list of upper preferable values andlower preferable values, this is to be understood as specificallydisclosing all ranges formed from any pair of any upper range limit orpreferred value and any lower range limit or preferred value, regardlessof whether ranges are separately disclosed. Where a range of numericalvalues is recited herein, unless otherwise stated, the range is intendedto include the endpoints thereof, and all integers and fractions withinthe range. It is not intended that the scope of the invention be limitedto the specific values recited when defining a range.

When the term “about” is used in describing a value or an end-point of arange, the disclosure should be understood to include the specific valueor end-point referred to.

As used herein, the terms “comprises,” “comprising,” “includes,”“including,” “containing,” “characterized by,” “has,” “having” or anyother variation thereof, are intended to cover a non-exclusiveinclusion. For example, a process, method, article, or apparatus thatcomprises a list of elements is not necessarily limited to only thoseelements but may include other elements not expressly listed or inherentto such process, method, article, or apparatus. Further, unlessexpressly stated to the contrary, “or” refers to an inclusive or and notto an exclusive or. For example, a condition A or B is satisfied by anyone of the following: A is true (or present) and B is false (or notpresent), A is false (or not present) and B is true (or present), andboth A and B are true (or present).

The transitional phrase “consisting of” excludes any element, step, oringredient not specified in the claim, closing the claim to theinclusion of materials other than those recited except for impuritiesordinarily associated therewith. When the phrase “consists of” appearsin a clause of the body of a claim, rather than immediately followingthe preamble, it limits only the element set forth in that clause; otherelements are not excluded from the claim as a whole.

The transitional phrase “consisting essentially of” limits the scope ofa claim to the specified materials or steps and those that do notmaterially affect the basic and novel characteristic(s) of the claimedinvention. “A ‘consisting essentially of’ claim occupies a middle groundbetween closed claims that are written in a ‘consisting of’ format andfully open claims that are drafted in a ‘comprising’ format.”

Where applicants have defined an invention or a portion thereof with anopen-ended term such as “comprising,” it should be readily understoodthat (unless otherwise stated) the description should be interpreted toalso describe such an invention using the terms “consisting essentiallyof” or “consisting of.”

Use of “a” or “an” are employed to describe elements and components ofthe invention. This is done merely for convenience and to give a generalsense of the invention. This description should be read to include oneor at least one and the singular also includes the plural unless it isobvious that it is meant otherwise.

In describing certain polymers it should be understood that sometimesapplicants are referring to the polymers by the monomers used to makethem or the amounts of the monomers used to make them or by the monomerresidues incorporated within them. While such a description may notinclude the specific nomenclature used to describe the final polymer ormay not contain product-by-process terminology, any such reference tomonomers, monomer residues, repeat units and amounts should beinterpreted to mean that the polymer is made from those monomers or thatamount of the monomers, and the corresponding polymers and compositionsthereof. In this regard, a reference to a copolymer containing residuesof a monomer is referring to the fact that the copolymer contains repeatunits from that monomer. When applicants refer to a copolymer containinga percentage of a monomer, it should be understood that this referenceis to the copolymer containing repeat units from that monomer.

In describing and/or claiming this invention, the term “copolymer” isused to refer to polymers containing two or more monomers.

The terms “finite amount” and “finite value” are used to refer to anamount that is greater than zero.

The term “acid copolymer” is used to refer to a resin compositioncomprised of copolymerized residues of an alpha olefin and copolymerizedresidues of an alpha, beta-ethylenically unsaturated carboxylic acidhaving 3 to 8 carbons. The term “ionomer” is used herein to refer to aresin composition derived from a partially or fully neutralized “acidcopolymer”. It should be understood that reference to “acid copolymer”is to a composition that is not so neutralized.

High Melt Flow Acid Copolymer Compositions

The invention is related to certain high melt flow acid copolymercompositions that are useful in forming safety interlayer sheets orsolar cell encapsulant films or sheets. Specifically, the high melt flowacid copolymer composition is comprised of an acid copolymer having a MIof about 75 to about 600 g/10 min as measured by ASTM D1238 at 190° C.and a 2160 g load. (A similar ISO test is ISO 1133.)

Acid copolymer Resins:

The high melt flow acid copolymer is comprised of a finite amount of analpha olefin and about 1 to about 30 wt % of an alpha,beta-ethylenicallyunsaturated carboxylic acid having 3 to 8 carbons, based on the totalweight of the copolymer. Preferably, the acid copolymer comprises about10 to about 25 wt %, or more preferably, about 15 to about 23 wt %, oryet more preferably, about 18 to about 23 wt %, of thealpha,beta-ethylenically unsaturated carboxylic acid, based on the totalweight of the acid copolymer.

The alpha olefin comonomers typically incorporate from 2 to 10 carbonatoms. Preferable alpha olefins include, but are not limited to,ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene,3-methyl-1-butene, 4-methyl-1-pentene, and the like and mixturesthereof. More preferably, the alpha olefin is ethylene. Thealpha,beta-ethylenically unsaturated carboxylic acid comonomers mayinclude acrylic acid, methacrylic acid, itaconic acid, maleic acid,maleic anhydride, fumaric acid, monomethyl maleic acid, and mixturesthereof. Preferable alpha,beta-ethylenically unsaturated carboxylic acidcomonomers include acrylic acid, methacrylic acid and mixtures thereof.The acid copolymers may be polymerized as disclosed in U.S. Pat. No.3,404,134; U.S. Pat. No. 5,028,674; U.S. Pat. No. 6,500,888; and U.S.Pat. No. 6,518,365.

The high melt flow acid copolymers have a MI of about 75 to about 600g/10 min, preferably about 100 to about 400 g/10 min.

Such a high melt flow rate provides the acid copolymer films or sheetsderived therefrom with reduced lamination temperatures, or shorter cycletime, or both, when they are used in safety laminates or solar celllaminates. Moreover, when laminated under the lamination temperaturesused herein, films or sheets derived from such high melt flow acidcopolymer compositions possess higher adhesion strength than thosederived from acid copolymer compositions with relatively lower melt flowrates.

The high melt flow acid copolymers may optionally contain otherunsaturated comonomers. Specific examples of preferable otherunsaturated comonomers include, but are not limited to, methyl acrylate,methyl methacrylate, ethyl acrylate, ethyl methacrylate, isopropylacrylate, isopropyl methacrylate, butyl acrylate, butyl methacrylate andmixtures thereof. In general, the acid copolymers may incorporate 0 toabout 50 wt %, or preferably, 0 to about 30 wt %, or more preferably, 0to about 20 wt %, of the other unsaturated comonomer(s), based on thetotal weight of the copolymer.

Additives:

The high melt flow acid copolymer composition may further comprise oneor more additives.

In one particular embodiment, the acid copolymer composition furthercomprises one or more silane coupling agents to further enhance theadhesion strength of the films or sheets derived therefrom.

Exemplary silane coupling agents that are useful in the inventioninclude, but are not limited to, gamma-chloropropylmethoxysilane,vinyltrimethoxysilane, vinyltriethoxysilane,vinyltris(beta-methoxyethoxy)silane,gamma-vinylbenzylpropyltrimethoxysilane,N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,gamma-methacryloxypropyltrimethoxysilane, vinyltriacetoxysilane,gamma-glycidoxypropyltrimethoxysilane,gamma-glycidoxypropyltriethoxysilane,beta-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, vinyltrichlorosilane,gamma-mercaptopropylmethoxysilane, gamma-aminopropyltriethoxysilane,N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, and the like andmixtures thereof. The silane coupling agents are preferably incorporatedin the acid copolymer compositions at a level of about 0.01 to about 5wt %, or more preferably, about 0.05 to about 1 wt %, based on the totalweight of the composition.

It is noted that the silane coupling agents can reduce the melt flowrate of the acid copolymer compositions to which they are incorporated.

Therefore, with a set level of silane, the high melt flow acid copolymercompositions can maintain a certain level of viscosity than the priorart lower melt flow acid copolymer compositions.

In another embodiment of the invention, the acid copolymer compositionsmay further comprise additives which effectively reduce the melt flow ofthe resin, to the limit of thermosetting the films or sheets duringlamination. The use of such additives will enhance the upper end-usetemperature and reduce creep of the laminate interlayer sheets or solarcell encapsulant films or sheets derived therefrom. Typically, theend-use temperature may be enhanced up to about 20 to about 70° C. Inaddition, safety laminates and solar cell laminates produced from suchmaterials will be fire resistant. Specifically, by thermosetting theacid copolymer resins during lamination, the resins will have a reducedtendency to melt and flow out of the laminate, which in turn, may serveas additional fuel for a fire.

Typically, the effective melt flow reducing additives are organicperoxides, such as 2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(tert-betylperoxy)hexane-3, di-tert-butyl peroxide,tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane,dicumyl peroxide, alpha, alpha′-bis(tert-butyl-peroxyisopropyl)benzene,n-butyl-4,4-bis(tert-butylperoxy)valerate,2,2-bis(tert-butylperoxy)butane, 1,1-bis(tert-butyl-peroxy)cyclohexane,1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane, tert-butylperoxybenzoate, benzoyl peroxide, and the like and mixtures combinationsthereof. Preferably the organic peroxides decompose at a temperature ofabout 100° C. or higher to generate radicals. More preferably, theorganic peroxides have a decomposition temperature which affords a halflife of 10 hours at about 70° C. or higher to provide improved stabilityfor blending operations.

Moreover, the temperature gap between the acid copolymer compositioncompounding temperature and the organic peroxide decompositiontemperature is critical to avoid premature crosslinking during thecompounding and film and sheet formation processes. In an extrusionprocess (which is the preferred process for producing the compositionsand manufacturing the high melt flow acid copolymer films or sheets),the high melt flow acid copolymer compositions require desirable reducedextrusion temperatures when compared to the otherwise lower melt flowacid copolymer compositions and therefore effectively preventingpremature crosslinking during extrusion compounding, film or sheetformation.

Preferably, the organic peroxides are added at a level of about 0.01 toabout 10 wt %, or preferably, about 0.5 to about 3.0 wt %, based on thetotal weight of the composition.

If desired, initiators, such as dibutyltin dilaurate, may also becontained in the acid copolymer composition at a level of about 0.01 toabout 0.05 wt %, based on the total weight of the composition. Inaddition, if desired, inhibitors, such as hydroquinone, hydroquinonemonomethyl ether, p-benzoquinone, and methylhydroquinone, may be addedfor the purpose of enhancing control to the reaction and stability.Typically, the inhibitors would be added at a level of less than about 5wt %, based on the total weight of the composition.

In yet another embodiment, the high melt flow acid copolymer compositionmay further comprise any other suitable additive(s) known within theart. Such additives may include, but are not limited to, plasticizers,processing aides, flow enhancing additives, lubricants, pigments, dyes,flame retardants, impact modifiers, nucleating agents, antiblockingagents (e.g., silica), thermal stabilizers, UV absorbers, UVstabilizers, dispersants, surfactants, chelating agents, couplingagents, adhesives, primers, reinforcement additives (e.g., glass fiber),fillers, and the like. Generally, when used in solar cell encapsulantfilms or sheets, the additives that may reduce the optical clarity ofthe compositions, such as reinforcement additives and fillers, arereserved for those films or sheets used as the back encapsulant layers.

Thermal stabilizers can be used and have been widely disclosed withinthe art. Any known thermal stabilizer may find utility within theinvention. Preferable general classes of thermal stabilizers include,but are not limited to, phenolic antioxidants, alkylated monophenols,alkylthiomethylphenols, hydroquinones, alkylated hydroquinones,tocopherols, hydroxylated thiodiphenyl ethers, alkylidenebisphenols, O—,N— and S-benzyl compounds, hydroxybenzylated malonates, aromatichydroxybenzyl compounds, triazine compounds, aminic antioxidants, arylamines, diaryl amines, polyaryl amines, acylaminophenols, oxamides,metal deactivators, phosphites, phosphonites, benzylphosphonates,ascorbic acid (vitamin C), compounds that destroy peroxide,hydroxylamines, nitrones, thiosynergists, benzofuranones, indolinones,and the like and mixtures thereof. The high melt flow acid copolymercompositions may contain any effective amount of thermal stabilizers.Use of a thermal stabilizer is optional and in some instances is notpreferred. When used, the high melt flow acid copolymer compositionscontain at least about 0.05 wt %, and up to about 10 wt %, morepreferably up to about 5 wt %, and most preferably up to about 1 wt %,of thermal stabilizers, based on the total weight of the composition.

UV absorbers can be used and have also been widely disclosed within theart. Any known UV absorber may find utility within the invention.Preferable general classes of UV absorbers include, but are not limitedto, benzotriazoles, hydroxybenzophenones, hydroxyphenyl triazines,esters of substituted and unsubstituted benzoic acids, and the like andmixtures thereof. The high melt flow acid copolymer compositions maycontain any effective amount of UV absorbers. Use of a UV absorber isoptional and in some instances is not preferred. When used, the highmelt flow acid copolymer compositions contain at least about 0.05 wt %,and up about 10 wt %, more preferably up to about 5 wt %, and mostpreferably up to about 1 wt %, of UV absorbers, based on the totalweight of the composition.

Hindered amine light stabilizers (HALS) can be used and have also beenwidely disclosed within the art. Generally, Hindered amine lightstabilizers are disclosed to be secondary, tertiary, acetylated,N-hydrocarbyloxy substituted, hydroxy substituted N-hydrocarbyloxysubstituted, or other substituted cyclic amines which furtherincorporate steric hindrance, generally derived from aliphaticsubstitution on the carbon atoms adjacent to the amine function. Thehigh melt flow acid copolymer compositions may contain any effectiveamount of hindered amine light stabilizers. Use of hindered amine lightstabilizers is optional and in some instances is not preferred. Whenused, the high melt flow acid copolymer compositions contain at leastabout 0.05 wt %, and up to about 10 wt %, more preferably up to about 5wt %, and most preferably, up to about 1 wt %, of hindered amine lightstabilizers, based on the total weight of the composition.

High Melt Flow Acid Copolymer Films or Sheets

The invention further provides shaped articles, such as, films or sheetscomprising the high melt flow acid copolymer compositions. These highmelt flow acid copolymer films and sheets may be produced by anysuitable process. For example, the films and sheets may be formedthrough dipcoating, solution casting, compression molding, injectionmolding, melts extrusions, melt blowing, or any other procedures thatare known to those of skill in the art. Preferably, the high melt flowacid copolymer films and sheets are formed by melt extrusion, which is aparticularly preferred process for formation of “endless” products.

As discussed above, the high melt flow acid copolymer films or sheetsare useful in forming the interlayer sheets in safety laminates orencapsulant films or sheets in solar cell laminates. Moreover, the highmelt flow acid copolymer films or sheets may take the form ofsingle-layer or multilayer films or sheets. By single-layer, it is meantthat the film or sheet has only one single layer and that the one singlelayer is made of the high melt flow acid copolymer composition. Bymultilayer, it is meant that the high melt flow acid copolymer film orsheet has two or more sub-layers and that at least one of the sub-layersis made of the high melt flow acid copolymer composition. The othersub-layer(s) of the multilayer film or sheet may be made of any suitablepolymeric compositions. Preferably, however, the other sub-layer(s) ismade of polymeric compositions selected from the group consisting ofacid copolymers and ionomers derived therefrom, poly(ethylene vinylacetate), poly(vinyl acetal) (e.g., poly(vinyl butyral)), polyurethane,polyvinylchloride, polyethylenes (e.g., metallocene-catalyzed linear lowdensity polyethylenes), polyolefin block elastomers, ethylene acrylateester copolymers (e.g., poly(ethylene-co-methyl acrylate) andpoly(ethylene-co-butyl acrylate)), silicone elastomers and epoxy resins.More preferably, the other sub-layers are formed of polymericcompositions selected from the group consisting of acid copolymers andionomers derived therefrom, poly(ethylene vinyl acetate),metallocene-catalyzed linear low density polyethylenes, polyolefin blockelastomers, and ethylene acrylate ester copolymers. Moreover, to provideadequate adhesion strength, at least one, or preferably, both, of thesurface sub-layers of the multilayer film or sheet are formed of thehigh melt flow acid copolymer compositions. In one preferred embodiment,multilayer films and sheets with high flow acid copolymer surfaces andlow flow core layers provide the desirable low lamination temperaturesand high adhesion of the invention.

The films or sheets of the invention preferably have a total thicknessof about 0.1 mil (0.003 mm) to about 250 mils (6.35 mm). When used as asafety laminate interlayer sheet, the high melt flow acid copolymersheet preferably has a total thickness of about 10 mils (0.25 mm) toabout 250 mils (6.35 mm), or more preferably, about 15 mils (0.38 mm) toabout 90 mils (2.28 mm), or yet more preferably, about 30 mils (0.76 mm)to about 60 mils (1.52 mm). Also in accordance to the invention, for useas a solar cell encapsulant the sheet or film preferably has a thicknessof about 0.1 mil (0.003 mm) to about 20 mils (0.51 mm). That is, whenused in a flexible solar cell laminate as a solar cell encapsulant film,the high melt flow acid copolymer film preferably has a total thicknessof about 0.1 mil (0.003 mm) to about 10 mils (0.25 mm), or morepreferably, about 1 mil (0.03 mm) to about 5 mils (0.13 mm), while whenused in a rigid solar cell laminate as a solar cell encapsulant sheet,the high melt flow acid copolymer sheet preferably has a total thicknessof about 10 mils (0.25 mm) to about 20 mils (0.51 mm). The thickness ofthe individual sub-layers that make up the total multilayer acidcopolymer film or sheet is not critical and may be independently varieddepending on the particular application. Preferably, however, thesurface layers of a multilayer film or sheet should have a thickness ofabout 1 mil (0.03 mm) to about 5 mils (0.13 mm).

The high melt flow acid copolymer films or sheets may have smooth orrough surfaces on one or both sides. Preferably, the high melt flowfilms or sheets have rough surfaces to facilitate the de-airing of thelaminates through the laminate process. Providing channels for theescape of air and removing air during lamination is a known method forobtaining laminates having acceptable appearance. Rough surfaces can beeffected by mechanically embossing or by melt fracture during extrusionof the interlayer sheet or encapsulant film or sheet followed byquenching so that the roughness is retained during handling. The surfacepattern can be applied to the high melt flow acid copolymer film orsheet through common art processes. For example, the as extruded film orsheet may be passed over a specially prepared surface of a die rollpositioned in close proximity to the exit of the die which imparts thedesired surface characteristics to one side of the molten polymer. Thus,when the surface of such roll has minute peaks and valleys, film orsheet formed of polymer cast thereon will have a rough surface on theside which contacts the roll which generally conforms respectively tothe valleys and peaks of the roll surface. Such die rolls are disclosedin, e.g., U.S. Pat. No. 4,035,549.

If desired, one or both surfaces of the high melt flow acid copolymerfilm or sheet may be treated to enhance the adhesion to other laminatelayers. This treatment may take any form known within the art, includingadhesives, primers, such as silanes, flame treatments (see, e.g., U.S.Pat. No. 2,632,921; U.S. Pat. No. 2,648,097; U.S. Pat. No. 2,683,894;and U.S. Pat. No. 2,704,382), plasma treatments (see e.g., U.S. Pat. No.4,732,814), electron beam treatments, oxidation treatments, coronadischarge treatments, chemical treatments, chromic acid treatments, hotair treatments, ozone treatments, ultraviolet light treatments, sandblast treatments, solvent treatments, and the like and combinationsthereof. For example, a thin layer of carbon may be deposited on one orboth surfaces of the film or sheet through vacuum sputtering asdisclosed in U.S. Pat. No. 4,865,711. U.S. Pat. No. 5,415,942, on theother hand, discloses a hydroxy-acrylic hydrosol primer coating that mayserve as an adhesion-promoting primer for poly(ethylene terephthalate)films.

The adhesive layer preferably can take the form of a monolayer of anadhesive primer or of a coating. The adhesive/primer coating may be lessthan 1 mil (0.03 mm), or preferably, less than 0.5 mil (0.013 mm), ormore preferably, less than 0.1 mil (0.003 mm), thick. The adhesives maybe any adhesive or primer known within the art. Preferably, theadhesives or primers are silane coupling agents or poly(vinyl amine) orpoly(allyl amine). The poly(allyl amine)-based primers and theirapplication to poly(ethylene terephthalate) polymeric films aredisclosed within U.S. Pat. No. 5,411,845; U.S. Pat. No. 5,770,312; U.S.Pat. No. 5,690,994; and U.S. Pat. No. 5,698,329.

Safety Laminates

The invention further provides safety laminates comprising a polymericinterlayer sheet formed of the high melt flow acid copolymercomposition.

Specifically, the safety laminate of the invention comprises at leastone rigid sheet layer and at least one layer of the high melt flow acidcopolymer sheet that is described above as an interlayer sheet.

As discussed above, at the lamination temperatures used herein, the highmelt flow acid copolymer interlayer sheets typically possess higheradhesion strength than those sheets derived from otherwise low melt flowacid copolymers, and therefore providing the safety laminate structureswith improved shock resistance.

In accordance to the invention, the rigid sheets can be glass or rigidplastic sheets, such as, polycarbonate, acrylics, polyacrylate, cyclicpolyolefins (e.g., ethylene norbornene polymers), metallocene-catalyzedpolystyrene, polyamides, polyesters, fluoropolymers and the like andcombinations thereof. Metal sheets (such as, aluminum, steel orgalvanized steel) or ceramic plates may be substituted for the rigidpolymeric sheet or glass.

The term “glass” is meant to include not only window glass, plate glass,silicate glass, sheet glass, low iron glass, tempered glass, temperedCeO-free glass, and float glass, but also to include colored glass,specialty glass (such as those include ingredients to control, e.g.,solar heating), coated glass (such as those sputtered with metals (e.g.,silver or indium tin oxide) for solar control purposes), E-glass,Toroglass, Solex® glass (a product of Solutia). Such specialty glassesare disclosed in, e.g., U.S. Pat. No. 4,615,989; U.S. Pat. No.5,173,212; U.S. Pat. No. 5,264,286; U.S. Pat. No. 6,150,028; U.S. Pat.No. 6,340,646; U.S. Pat. No. 6,461,736; and U.S. Pat. No. 6,468,934. Itis understood, however, that the type of glass to be selected for aparticular laminate depends on the intended use.

One preferred embodiment of the invention is a safety laminatecomprising at least one layer of glass, and at least one layer of thehigh melt flow acid copolymer sheet described above. Preferably, thehigh melt flow acid copolymer sheet is self-adhered to the glass. Asused herein, when the a polymeric sheet is said to be “self-adhered” tothe glass, it is meant that there is no intermediate layer such as aprimer or thin adhesive layer between the glass and the polymeric layer,nor has the surface of the glass or polymeric layer been speciallytreated. A more preferred embodiment of the invention is a laminatecomprising two layers of glass and at least one layer of the high meltflow acid copolymer sheets bonded in between. Preferably, the high meltflow acid copolymer sheet is self-adhered to one or both of the glasslayers.

The safety laminate of the invention may further comprise other optionalinterlayer sheets and/or film layers. The other optional interlayersheets may be formed of any suitable materials, such as, acid copolymersand ionomers derived therefrom, poly(ethylene vinyl acetate), poly(vinylacetal) (e.g., poly(vinyl butyral)), polyurethane, polyvinylchloride,polyethylenes (e.g., metallocene-catalyzed linear low densitypolyethylenes), polyolefin block elastomers, ethylene acrylate estercopolymers (e.g., poly(ethylene-co-methyl acrylate) andpoly(ethylene-co-butyl acrylate)), silicone elastomers and epoxy resins.In one preferred embodiment, the other interlayer is an acid copolymercomposition comprising acid copolymer of an alpha olefin and about 1 toabout 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acidhaving 3 to 8 carbons, based on the total weight of the acid copolymer,wherein the acid copolymer has a Melt Index of about 75 to about 600g/10 min, and may be the same or different than the one used in thefirst layer. The thickness of the other optional interlayer sheet(s) isnot critical and may be independently varied depending on the particularapplication. The values provided above for the acid copolymer layer arepreferred in many instances.

The film layers used in the safety laminates may be metal, such asaluminum foil, or polymeric. Preferable polymeric film materialsinclude, but are not limited to, polyesters (e.g., poly(ethyleneterephthalate) (PET)), poly(ethylene naphthalate), polycarbonate,polyolefins (e.g., polypropylene, polyethylene, and cyclic polyolefins),norbornene polymers, polystyrene (including syndiotactic polystyrene),styrene-acrylate copolymers, acrylonitrile-styrene copolymers,polysulfones (e.g., polyethersulfone, polysulfone, etc.), nylons,poly(urethanes), acrylics, cellulose acetates (e.g., cellulose acetate,cellulose triacetates, etc.), cellophane, vinyl chloride polymers (e.g.,polyvinylidene chloride, vinylidene chloride copolymers, etc.),fluoropolymers (e.g., polyvinyl fluoride, polyvinylidene fluoride,polytetrafluoroethylene, ethylene-tetrafluoroethylene copolymers, etc.)and the like. More preferably, the polymeric film is a biaxiallyoriented poly(ethylene terephthalate) film.

The thickness of the polymeric film is not critical and may be varieddepending on the particular application. In general, however, thethickness of the polymeric film may range from about 0.1 mils (0.003 mm)to about 10 mils (0.26 mm), or preferably, from about 1 mil (0.025 mm)to about 7 mils (0.18 mm).

In addition, the polymeric films are sufficiently stress-relieved andshrink-stable under the coating and lamination processes. Preferably,the polymeric films are heat stabilized to provide low shrinkagecharacteristics when subjected to elevated temperatures (i.e. less than2% shrinkage in both directions after 30 min at 150° C.).

The films may also be coated if desired. For example, the films may becoated with organic infrared absorbers and sputtered metal layers, suchas silver, coatings and the like. Metal coated polymeric films aredisclosed in, e.g., U.S. Pat. No. 3,718,535; U.S. Pat. No. 3,816,201;U.S. Pat. No. 4,465,736; U.S. Pat. No. 4,450,201; U.S. Pat. No.4,799,745; U.S. Pat. No. 4,846,949; U.S. Pat. No. 4,954,383; U.S. Pat.No. 4,973,511; U.S. Pat. No. 5,071,206; U.S. Pat. No. 5,306,547; U.S.Pat. No. 6,049,419; U.S. Pat. No. 6,104,530; U.S. Pat. No. 6,204,480;U.S. Pat. No. 6,255,031; and U.S. Pat. No. 6,565,982. For example, thecoating may function as oxygen and moisture barrier coatings, such asthe metal oxide coating disclosed within U.S. Pat. No. 6,521,825; U.S.Pat. No. 6,818,819; and EP 1 182 710.

If desired, one or both surfaces of laminate layers, such as the acidcopolymer interlayer sheet(s), the optional other interlayer sheet(s) orfilm layer(s), or the rigid sheet(s), may be treated to enhance theiradhesion strength, as described above.

The safety laminate of the invention may take any form known within theart. Preferable specific glass laminate constructions include, forexample, wherein “HMFAC” means the preferable high melt flow acidcopolymer comprising interlayer sheet and multilayer sheet, as describedabove,

-   -   glass/HMFAC;    -   glass/HMFAC/film;    -   glass/HMFAC/glass;    -   glass/HMFAC/film/HMFAC/glass;    -   glass/HMFAC/film/HMFAC/film;        and the like.

The safety laminates of the invention may be produced by any of thelamination process that are described below in detail, or by otherprocesses.

Solar Cell Pre-Laminate Assemblies and Solar Cell Laminates

The invention further provides a solar cell pre-laminate assembly whichcomprises a solar cell component formed of one or a plurality solarcells and at least one layer of the high melt flow acid copolymer filmor sheet that is described above.

Solar cells are commonly available on an ever increasing variety as thetechnology evolves and is optimized. Within the invention, a “solarcell” is meant to include any article which can convert light intoelectrical energy. Typical art examples of the various forms of solarcells include, for example, single crystal silicon solar cells,polycrystal silicon solar cells, microcrystal silicon solar cells,amorphous silicon based solar cells, copper indium selenide solar cells,compound semiconductor solar cells, dye sensitized solar cells, and thelike. The most common types of solar cells include multi-crystallinesolar cells, thin film solar cells, compound semiconductor solar cellsand amorphous silicon solar cells due to relatively low costmanufacturing ease for large scale solar cells.

Thin film solar cells are typically produced by depositing several thinfilm layers onto a substrate, such as glass or a flexible film, with thelayers being patterned so as to form a plurality of individual cellswhich are electrically interconnected to produce a suitable voltageoutput. Depending on the sequence in which the multi-layer deposition iscarried out, the substrate may serve as the rear surface or as a frontwindow for the solar cell module. By way of example, thin film solarcells are disclosed in U.S. Pat. No. 5,512,107; U.S. Pat. No. 5,948,176;U.S. Pat. No. 5,994,163; U.S. Pat. No. 6,040,521; U.S. Pat. No.6,137,048; and U.S. Pat. No. 6,258,620. Examples of thin film solar cellmodules are those that comprise cadmium telluride or CIGS,(Cu(In—Ga)(SeS)2), thin film cells.

In one particular embodiment, the solar cell pre-laminate assemblycomprises one layer of the high melt flow acid copolymer film or sheet,which is positioned next to the solar cell component and serves as oneof the encapsulant layers, or preferably, the high melt flow acidcopolymer film or sheet is positioned next to the solar cell componentat the light-receiving side and serves as the front encapsulant layer.

In accordance to the invention, besides the at least one high melt flowacid copolymer film or sheet, the solar cell pre-laminate assembly mayoptionally further comprise encapsulant layers formed of other polymericmaterials, such as, acid copolymers and ionomers derived therefrom,poly(ethylene vinyl acetate), poly(vinyl acetal) (e.g., poly(vinylbutyral), including acoustic grades of poly(vinyl butyral)),polyurethane (PU), poly vinyl chloride, polyethylenes (e.g., linear lowdensity metallocene-catalyzed polyethylenes), polyolefin blockelastomers, ethylene acrylate ester copolymers (e.g.,poly(ethylene-co-methyl acrylate) and poly(ethylene-co-butyl acrylate)),silicone elastomers and epoxy resins.

In a further embodiment, the solar cell pre-laminate assembly comprisestwo layers of the high melt flow acid copolymer film or sheet, whereineach of the two high melt flow acid copolymer films or sheets arelaminated to each of the two sides of the solar cell component and serveas the front and back encapsulant layers.

The thickness of the individual encapsulant layers other than the highmelt flow acid copolymer film(s) or sheet(s) is not critical and may beindependently varied depending on the particular application.Preferably, the thickness of each of these encapsulant layers mayindependently range from about 1 mil (0.026 mm) to about 120 mils (3.00mm), or more preferably, from about 1 mil to about 40 mils (1.02 mm), ormost preferably, from about 1 mil to about 20 mils (0.51 mm). Inaddition, all the encapsulant layer(s) comprised in the solar cellpre-laminate assemblies, may have smooth or roughened surfaces.Preferably, however, the encapsulant layer(s) have roughened surfaces tofacilitate the de-airing of the laminates through the laminationprocess.

In yet a further embodiment, the solar cell pre-laminate assembly mayfurther comprise an incident layer and/or a backing layer serving as theouter layers of the assembly at the light-receiving side and the backside, respectively.

The outer layers of the solar cell pre-laminate assemblies, i.e., theincident layers and the backing layer, may be derived from any suitablesheets or films. Suitable sheets may be glass or plastic sheets, suchas, polycarbonate, acrylics, polyacrylate, cyclic polyolefins (e.g.,ethylene norbornene polymers), metallocene-catalyzed polystyrene,polyamides, polyesters, fluoropolymers and the like and combinationsthereof. In addition, metal sheets, such as aluminum, steel, galvanizedsteel, or ceramic plates may be utilized in forming the back-sheet.

Suitable film layers may be polymeric. Preferred polymers used to formthe polymeric films, include but are not limited to, polyesters (e.g.,poly(ethylene terephthalate)), poly(ethylene naphthalate),polycarbonate, polyolefins (e.g., polypropylene, polyethylene, andcyclic polyolefins), norbornene polymers, polystyrene (includingsyndiotactic polystyrene), styrene-acrylate copolymers,acrylonitrile-styrene copolymers, polysulfones (e.g., polyethersulfone,polysulfone, etc.), nylons, poly(urethanes), acrylics, celluloseacetates (e.g., cellulose acetate, cellulose triacetates, etc.),cellophane, vinyl chloride polymers (e.g., polyvinylidene chloride,vinylidene chloride copolymers, etc.), fluoropolymers (e.g., polyvinylfluoride, polyvinylidene fluoride, polytetrafluoroethylene,ethylene-tetrafluoroethylene copolymers, etc.) and the like. Mostpreferably, the polymeric film is biaxially oriented polyester film(preferably poly(ethylene terephthalate film) or a fluoropolymer film(e.g., Tedlar®, Tefzel®, and Teflon® films, from E. I. du Pont deNemours and Company, Wilmington, Del. (DuPont)).Fluoropolymer-polyester-fluoropolymer (“TPT”) films are also preferredfor some applications. Metal films, such as aluminum foil may also beused herein as the back-sheet.

The solar cell pre-laminate assembly of the invention, may optionallyfurther comprise other functional film or sheet layers (e.g., dielectriclayers or barrier layers) embedded within the assembly. Such functionallayers may be derived from any of the above mentioned polymeric films orthose that are coated with additional functional coatings. For example,poly(ethylene terephthalate) films coated with a metal oxide coating,such as those disclosed within U.S. Pat. No. 6,521,825; U.S. Pat. No.6,818,819; and EP 1 182 710, may function as oxygen and moisture barrierlayers in the laminates.

If desired, a layer of non-woven glass fiber (scrim) may also beincluded in the solar cell laminates to facilitate de-airing during thelamination process or to serve as reinforcement for the encapsulantlayer(s). The use of such scrim layers within solar cell laminates isdisclosed within, e.g., U.S. Pat. No. 5,583,057; U.S. Pat. No.6,075,202; U.S. Pat. No. 6,204,443; U.S. Pat. No. 6,320,115; U.S. Pat.No. 6,323,416; and EP 0 769 818.

In addition, it is understood that all the film or sheet layerspositioned to the light-receiving side of the solar cell layer are madeof transparent material to allow efficient transmission of sunlight intothe solar cell component. In some instances, a special film or sheet maybe included to serve both the function of an encapsulant layer and anouter layer. It is also conceivable that any of the film or sheet layersincluded in the assembly may be in the form of a pre-formed single-layeror multi-layer film or sheet.

If desired, one or both surfaces of the laminate layers of the solarcell pre-laminate assemblies may be treated to enhance the adhesionstrength, as described above.

The solar cell pre-laminate assemblies may take any form known withinthe art. Preferable specific solar cell pre-laminate constructions (top(light incident) side to back side) include, for example, wherein“HMFAC” means the high melt flow acid copolymer encapsulant film,multilayer film, sheet and multilayer sheet of the invention, asdescribed above,

-   -   glass/HMFAC/solar cell/HMFAC/glass;    -   glass/HMFAC/solar cell/HMFAC/Tedlar® film;    -   Tedlar®film/HMFAC/solar cell/HMFAC/glass;    -   Tedlar® film/HMFAC/solar cell/HMFAC/Tedlar® film;    -   glass/HMFAC/solar cell/HMFAC/PET film;    -   Tedlar® film/HMFAC/solar cell/HMFAC/PET film;    -   glass/HMFAC/solar cell/HMFAC/barrier coated film/HMFAC/glass;    -   Tedlar® film/HMFAC/barrier coated film/HMFAC/solar        cell/HMFAC/barrier coated film/HMFAC/Tedlar® film;    -   glass/HMFAC/solar cell/HMFAC/aluminum stock;    -   Tedlar® film/HMFAC/solar cell/HMFAC/aluminum stock;    -   glass/HMFAC/solar cell/HMFAC/galvanized steel sheet;    -   glass/HMFAC/solar cell/HMFAC/PET film/HMFAC/aluminum stock;    -   Tedlar® film/HMFAC/solar cell/HMFAC/PET film/HMFAC/aluminum        stock;    -   glass/HMFAC/solar cell/HMFAC/PET film/HMFAC/galvanized steel        sheet;    -   Tedlar® film/HMFAC/solar cell/HMFAC/PET film/HMFAC/galvanized        steel sheet;    -   glass/HMFAC/solar cell/acoustic poly(vinyl butyral) encapsulant        layer/glass;    -   glass/HMFAC/solar cell/poly(vinyl butyral) encapsulant        layer/Tedlar® film;    -   Tedlar® film/HMFAC/solar cell/acid copolymer encapsulant        layer/Tedlar® film;    -   glass/HMFAC/solar cell/ethylene vinyl acetate encapsulant        layer/PET film;    -   Tedlar® film/HMFAC/solar cell/poly(ethylene-co-methyl acrylate)        encapsulant layer/PET film;    -   glass/poly(ethylene-co-butyl acrylate) encapsulant layer/solar        cell/HMFAC/barrier coated film/poly(ethylene-co-butyl acrylate)        encapsulant layer/glass;        and the like. While reference in the above examples is to the        preferred Tedlar® fluoropolymer film, it should be readily        recognized that the above embodiments can also be made with        other fluoropolymer film, such as a        fluoropolymer-polyester-fluoropolymer trilayer film. While        reference in the above examples is to the preferred        poly(terephthalate) film, it should be readily recognize that        any polyester film can be used. In addition, the term “glass” is        intended to refer to sheets of any of the aforementioned types        of glass or glass alternatives.

The invention further provides solar cell laminates derived from thesolar cell pre-laminate assemblies disclosed above. Specifically thesolar cell laminates are formed by subjecting the solar cellpre-laminate assemblies to further lamination process, as provided belowin detail.

Moreover, as discussed above, under the lamination temperature usedherein, the high melt flow acid copolymer encapsulant films or sheetstypically possess higher adhesion strength than those encapsulant filmsor sheets derived from otherwise low melt flow acid copolymers at thereduced lamination conditions described herein, and therefore providesolar cell laminate structures with a simplified production process.

Lamination Process

The invention further provides a simplified process for producing thesafety laminates or solar cell laminates. Specifically, as providedabove, the incorporation of the high melt flow acid copolymer interlayersheets or high melt flow acid copolymer solar cell encapsulant films orsheets requires reduced lamination temperatures, or cycle time, or bothcompared to the lamination temperatures or cycle times used in theprocess involving low melt flow acid copolymers.

In accordance to the invention, the lamination process may be anautoclave or non-autoclave process.

In an exemplary process, a glass sheet, a front encapsulant layer, asolar cell component, a back encapsulant layer and a backing layer(e.g., Tedlar® film), and a cover glass sheet are laid up and laminatedtogether under heat and pressure and a vacuum (for example, in the rangeof about 27-28 inches (689-711 mm) Hg) to remove air. Preferably, theglass sheet has been washed and dried. A typical glass type is 90 milthick annealed low iron glass. In an exemplary procedure, thepre-laminate assembly of the invention is placed into a bag capable ofsustaining a vacuum (“a vacuum bag”), drawing the air out of the bagusing a vacuum line or other means of pulling a vacuum on the bag,sealing the bag while maintaining the vacuum, placing the sealed bag inan autoclave at a temperature of about 100° C. to about 180° C., at apressure of about 150- about 250 psi, preferably about 200 psi (about 15bars), for about 10 to about 50 minutes. Preferably the bag isautoclaved at a temperature of about 100° C. to about 120° C. for about20 to about 45 minutes. More preferably the bag is autoclaved at atemperature of about 110° C. to about 120° C. for about 20 to about 40minutes. A vacuum ring may be substituted for the vacuum bag. One typeof vacuum bags is disclosed within U.S. Pat. No. 3,311,517. The highmelt flow acid copolymer films and sheets of the invention provides thedesirable advantage of lower lamination temperatures and/or fasterlamination cycle times, depending on the laminator's choice.

Any air trapped within the pre-laminate assembly may be removed througha nip roll process. For example, the pre-laminate assembly may be heatedin an oven at a temperature of about 80° C. to about 120° C., orpreferably, at a temperature of between about 90° C. and about 100° C.,for about 15-60 (preferably about 30) minutes. Thereafter, the heatedpre-laminate assembly is passed through a set of nip rolls so that theair in the void spaces between the solar cell outside layers, the solarcell component, and the encapsulant layers may be squeezed out, and theedge of the assembly sealed. This process may provide the final solarcell module or may provide what is referred to as a pre-press assembly,depending on the materials of construction and the exact conditionsutilized.

The pre-press assembly may then be placed in an air autoclave where thetemperature is raised to about 100° C. to about 160° C., or preferably,between about 110° C. and about 120° C., and pressure to between about100 psig and about 300 psig, or preferably, about 200 psig (14.3 bar).These conditions are maintained for about 15 minutes to about 1 hour, orpreferably, about 20 to about 50 minutes, after which, the air is cooledwhile no more air is added to the autoclave. After about 10-30(preferably about 20) minutes of cooling, the excess air pressure isvented and the solar cell laminates are removed from the autoclave. Thisshould not be considered limiting. Essentially any lamination processknown within the art may be used herein.

A non-autoclave lamination process has been disclosed, e.g., within U.S.Pat. No. 3,234,062; U.S. Pat. No. 3,852,136; U.S. Pat. No. 4,341,576;U.S. Pat. No. 4,385,951; U.S. Pat. No. 4,398,979; U.S. Pat. No.5,536,347; U.S. Pat. No. 5,853,516; U.S. Pat. No. 6,342,116; U.S. Pat.No. 5,415,909; US 2004-0182493; US 2003-0148114 A1; EP 1 235 683 B1; WO91/01880; and WO 03/057478 A1. Generally, the non-autoclave processincludes heating the pre-laminate assembly or the pre-press assemblyand, optionally, the application of vacuum, pressure or both. Forexample, the pre-press may be successively passed through heating ovensand nip rolls. A commercial example of a photovoltaic lamination processincludes the Icolam vacuum laminating systems of Meier VakuumtechnikGmbH (Bocholt, Germany).

In producing solar cell laminates, if desired, the edges of thelaminates may be sealed to reduce moisture and air intrusion and thepotential degradation effect on the efficiency and lifetime of the solarcell(s) by any means disclosed within the art. Suitable edge sealmaterials include, but are not limited to, butyl rubber, polysulfide,silicone, polyurethane, polypropylene elastomers, polystyreneelastomers, block elastomers, styrene-ethylene-butylene-styrene (SEBS),and the like.

EXAMPLES

The following Examples and are intended to be illustrative of theinvention, and are not intended in any way to limit the scope of theinvention.

Methods

The following methods are used in the Examples presented hereafter.

Melt Index

Melt Index (MI) is measured by ASTM D1238 at 190° C. and a 2160 g load.A similar ISO test is ISO 1133.

I. Lamination Process 1:

The laminate layers described below are stacked (laid up) to form thepre-laminate assembly described within the examples. For the assemblycontaining a film layer as the incident or back-sheet layer, a coverglass sheet is placed over the film layer. The pre-laminate assembly isthen placed within a Meier ICOLAM 10/ 08 laminator (Meier VakuumtechnikGmbH, Bocholt, Germany). The lamination cycle includes an evacuationstep (vacuum of 3 in. Hg) of 5.5 minutes and a pressing stage (pressureof 1000 mb) of 5.5 minutes at a temperature of 115° C. For Examples 9,11, 41 and 43 only, an additional step at 145° C. for 5 minutes whilemaintaining the pressing conditions is incorporated to cure thecomposition. The laminate is then removed.

II. Lamination Process 2:

The laminate layers described below are stacked (laid up) to form thepre-laminate assemblies described within the examples. For the assemblycontaining a film layer as the incident or back-sheet layer, a coverglass sheet is placed over the film layer. The pre-laminate assembly isthen placed within a vacuum bag, the vacuum bag is sealed and a vacuumis applied to remove the air from the vacuum bag. The bag is placed intoan oven and heated to 90-100° C. for 30 minutes to remove any aircontained between the assembly. The pre-press assembly is then subjectedto autoclaving at 115° C. for 30 minutes in an air autoclave to apressure of 200 psig (14.3 bar), as described above. The air is thencooled while no more air is added to the autoclave. After 20 minutes ofcooling when the air temperature reaches less than about 50° C., theexcess pressure is vented, and the laminate is removed from theautoclave.

Examples 1-15

The 12×12 in (305×305 mm) laminate structures described below in Table 1are assembled and laminated by Lamination Process 1, above.

TABLE 1 Laminate Structures Example Layer 1 Layer 2 Layer 3 Layer 4Layer 5  1, 16 Glass 1 HMFAC 1 HMFAC 1 Glass 1  2, 17 Glass 1 HMFAC 2Glass 1  3, 18 Glass 2 HMFAC 3 PET 1 HMFAC 3 Glass 2  4, 19 Glass 3HMFAC 4 EVA HMFAC 4 Glass 1  5, 20 Glass 1 HMFAC 5 HMFAC 5 PET 2  6, 21Glass 2 HMFAC 6 Glass 2  7, 22 Glass 1 HMFAC 7 PET 3  8, 23 Glass 1HMFAC 8 EBA HMFAC 8 Glass 1  9, 24 Glass 1 HMFAC 9 Glass 1 10, 25 Glass2 HMFAC 10 PET 4 PVB PET 1 11, 26 Glass 1 HMFAC 12 HMFAC 11 HMFAC 12Glass 1 12, 27 Glass 2 HMFAC 13 EBA HMFAC 13 PET 5 13, 28 Glass 1 HMFAC14 PET 6 HMFAC 14 Glass 1 14, 29 Glass 3 HMFAC 15 PET 1 HMFAC 15 Glass 215, 30 Glass 1 HMFAC 16 HMFAC 16 Glass 1

-   -   HMFAC 1 is a 20 mil (0.51 mm) thick embossed sheet of Acid        Copolymer A, a poly(ethylene-co-methacrylic acid) containing 15        wt % of polymerized residues of methacrylic acid and having a MI        of 100 g/10 min.    -   HMFAC 2 is a 60 mil (1.52 mm) thick embossed tri-layer sheet        having (i) two (2) 1 mil (0.03 mm) thick surface layers formed        of a blend of Acid Copolymer B, a poly(ethylene-co-methacrylic        acid) containing 18 wt % of polymerized residues of methacrylic        acid and having a MI of 220 g/10 min, and 0.15 wt % of TINUVIN        328 (Ciba Specialty Chemicals Company), based on the total        weight of the blend and (ii) a core layer of a        poly(ethylene-co-isobutyl acrylate-co-methacrylic acid)        containing 10 wt % of polymerized residues of isobutyl acrylate        and 10 wt % of polymerized residues of methacrylic acid that is        70% neutralized with zinc ions and having a MI of 1 g/10 min.    -   HMFAC 3 is a 15 mil (0.38 mm) thick embossed tri-layer sheet        having (i) two (2) 1 mil (0.03 mm) thick surface layers of Acid        Copolymer C, poly(ethylene-co-methacrylic acid) containing 22        wt% of polymerized residues of methacrylic acid and having a MI        of 400 g/10 min and (ii) a core layer of a        poly(ethylene-co-n-butyl acrylate) containing 35 wt % of n-butyl        acrylate and having a MI of 3 g/10 min.    -   HMFAC 4 is a 1 mil (0.03 mm) thick film of Acid Copolymer D, a        poly(ethylene-co-methacrylic acid) containing 19 wt % of        polymerized residues of methacrylic acid and having a MI of 150        g/10 min.    -   HMFAC 5 is a 20 mil (0.51 mm) thick embossed sheet of Acid        Copolymer E, a composition comprising 99.5 wt % of Acid        Copolymer A and 0.5 wt % of        N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, based on        the total weight of the composition.    -   HMFAC 6 is a 90 mil (2.25 mm) thick embossed tri-layer sheet        having (i) two (2) 1 mil (0.03 mm) thick surface layers of Acid        Copolymer F, a composition comprising 99.25 wt % of Acid        Copolymer B and 0.25 wt % of        N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, based on        the total weight of the composition and (ii) a core layer of a        poly(ethylene-co-methacrylic acid) containing 22 wt% of        polymerized residues of methacrylic acid that is 35% neutralized        with sodium ion and having a MI of 1.5 g/10 min.    -   HMFAC 7 is a 20 mil (0.51 mm) thick embossed tri-layer sheet        having (i) two (2) 1 mil (0.03 mm) thick surface layers of Acid        Copolymer G, a composition comprising 99.875 wt % of Acid        Copolymer C and 0.125 wt % of        N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, based on        the total weight of the composition and (ii) a core layer of        poly(ethylene-co-methyl acrylate) containing 25 wt % of        polymerized residues of methyl acrylate and having a MI of 5        g/10 min.    -   HMFAC 8 is a 1 mil (0.03 mm) thick film of Acid Copolymer H, a        composition comprising 99.875 wt % of Acid Copolymer D, 0.30 wt        % of TINUVIN 1577, 0.30 wt % of CHIMASSORB 944 (products of the        Ciba Specialty Chemicals Company), and 0.125 wt % of        gamma-glycidoxypropyltriethoxysilane, based on the total weight        of the composition.    -   HMFAC 9 is a 90 mil (2.25 mm) thick embossed tri-layer sheet        having (i) two (2) 1 mil (0.03 mm) thick surface layers of Acid        Copolymer E and (ii) a core layer of Acid Copolymer I, a        composition comprising 98.5 wt % of Acid Copolymer A and 1.5 wt        % of 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on        the total weight of the composition.    -   HMFAC 10 is a 15 mil (0.38 mm) thick embossed sheet of Acid        Copolymer J, a composition comprising 98.0 wt % of Acid        Copolymer B and 2.0 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 11 is a 20 mil (0.51 mm) thick embossed sheet of Acid        Copolymer K, a composition comprising 95 wt % of Acid Copolymer        C, 0.5 wt % of CYASORB UV-1164 (Cytec Industries), 2.5 wt % of        trimethylolpropane triacrylate, and 2.5 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 12 is a 1 mil (0.03 mm) thick film of Acid Copolymer L, a        composition comprising 93.0 wt % of Acid Copolymer D, 5.0 wt %        of triallyl isocyanurate and 2.0 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 13 is a 1 mil (0.03 mm) thick film of Acid Copolymer M, a        composition comprising 98.0 wt % of Acid Copolymer A, 0.5 wt %        of vinyltrimethoxysilane, and 1.5 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 14 is a 20 mil (0.51 mm) thick embossed sheet of Acid        Copolymer N, a composition comprising 97.75 wt % of Acid        Copolymer B, 0.25 wt % of        gamma-methacryloxypropyltrimethoxysilane, and 2.0 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 15 is a 15 mil (0.38 mm) thick embossed sheet of Acid        Copolymer O, a composition comprising 97.375 wt % of Acid        Copolymer C, 0.125 wt % of        N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,        and 2.5 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   HMFAC 16 is a 90 mil (2.25 mm) thick embossed sheet of Acid        Copolymer P, a composition comprising 94.875 wt % of Acid        Copolymer D, 3 wt % of trimethylolpropane triacrylate, 0.125 wt        % of        N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,        CYASORB UV-1164, and TINUVIN 123, and 2.0 wt % of        1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, based on the        total weight of the composition.    -   EBA is a 30 mil (0.76 mm) thick sheet formed of a        poly(ethylene-co-n-butyl acrylate) containing 30 wt % of        polymerized residues of n-butyl acrylate and having a MI of 2        g/10 min.    -   EVA is SC50B, believed to be a formulated composition based on        poly(ethylene-co-vinyl acetate) in the form of a 20 mil thick        (0.51 mm) sheet (Hi-Sheet Corporation, formerly Mitsui Chemicals        Fabro, Inc.).    -   Glass 1 is 2.5 mm thick float glass.    -   Glass 2 is a 2.5 mm thick clear annealed float glass plate        layer.    -   Glass 3 in a 3.0 mm thick Solex® solar control glass.    -   PET 1 is a 7 mils (0.18 mm) thick poly(allyl amine)-primed,        biaxially-oriented poly(ethylene terephthalate) film layer.    -   PET 2 is a XIR®-70 HP Auto film (Southwall Company).    -   PET 3 is a XIR®-75 Auto Blue V-1 film (Southwall Company).    -   PET 4 is a Soft Look® UV/IR 25 solar control film (Tomoegawa        Paper Company, Ltd., of Tokyo, Japan).    -   PET 5 is a XIR®-75 Green film (Southwall Company).    -   PET 6 is RAYBARRIER® TFK-2583 solar control film (Sumitomo Osaka        Cement Company).    -   PVB is B51V, believed to be a formulated composition based on        poly(vinyl butyral) in the form of a 20 mil thick (0.51 mm)        sheet (DuPont).

Examples 16-30

The 12×12 in (305×305 mm) laminate structures described above in Table 1are assembled and laminated by Lamination Process 2, above.

Examples 31-43

The 12×12 in (305×305 mm) solar cell laminate structures described belowin Table 2 are assembled and laminated by Lamination Process 1, above.Layers 1 and 2 constitute the incident layer and front-sheet encapsulantlayer, respectively, and Layers 4 and 5 constitute the back-sheetencapsulant layer and the backing layer, respectively.

TABLE 2 Solar Cell Laminate Structures Example Layer 1 Layer 2 Layer 3Layer 4 Layer 5 31, 44 Glass 4 HMFAC 1 Solar Cell 1 HMFAC 1 FPF 32, 45Glass 4 EVA Solar Cell 2 HMFAC 2 Glass 1 33, 46 Glass 4 HMFAC 3 SolarCell 3 HMFAC 2 AL 34, 47 FPF HMFAC 4 Solar Cell 1 HMFAC 4 FPF 35, 48Glass 1 HMFAC 5 Solar Cell 2 HMFAC 5 PET 1 36, 49 Glass 4 HMFAC 7 SolarCell 3 HMFAC 6 FPF 37, 50 FPF HMFAC 8 Solar Cell 3 HMFAC 8 FPF 38, 51Glass 2 HMFAC 10 Solar Cell 4 HMFAC 9 Glass 2 39, 52 Glass 4 HMFAC 11Solar Cell 1 HMFAC 11 FPF 40, 53 FPF HMFAC 12 Solar Cell 2 HMFAC 12 PET1 41, 54 FPF HMFAC 13 Solar Cell 4 HMFAC 13 FPF 42, 55 Glass 4 HMFAC 14Solar Cell 1 HMFAC 14 Glass 1 43, 56 Glass 4 HMFAC 15 Solar Cell 4 HMFAC16

-   -   AL is a 3.2 mm thick aluminum sheet (3.2 mm thick) that is 5052        alloyed with 2.5 wt % of magnesium and conforms to Federal        specification QQ-A-250/8 and ASTM B209.    -   FPF is a 1.5 mil (0.038 mm) thick corona surface treated Tedler®        film, DuPont.    -   Glass 4 is Starphire® glass from the PPG Corporation.    -   Solar Cell 1 is a 10-inch by 10-inch amorphous silicon        photovoltaic device comprising a stainless steel substrate (125        micrometers thick) with an amorphous silicon semiconductor layer        (see, e.g., U.S. Pat. No. 6,093,581, Example 1).    -   Solar Cell 2 is a 10-inch by 10-inch copper indium diselenide        (CIS) photovoltaic device (see, e.g., U.S. Pat. No. 6,353,042,        column 6, line 19).    -   Solar Cell 3 is a 10-inch by 10-inch cadmium telluride (CdTe)        photovoltaic device (see, e.g., U.S. Pat. No. 6,353,042, column        6, line 49).    -   Solar Cell 4 is a silicon solar cell made from a 10-inch by        10-inch polycrystalline EFG-grown wafer (see, e.g., U.S. Pat.        No. 6,660,930, column 7, line 61).

Examples 44-56

The 12×12 in (305×305 mm) solar cell laminate structures described abovein Table 2 are assembled and laminated by Lamination Process 2, above.Layers 1 and 2 constitute the incident layer and the front-sheetencapsulant layer, respectively, and Layers 4 and 5 constitute theback-sheet encapsulant layer and the backing layer, respectively.

Comparative Example CE1 and Example 57

In Comparative Example CE1, 50 grams of a poly(ethylene-co-methacrylicacid) copolymer containing 12 wt % polymerized residues of methacrylicacid and having a MI of 3.3 g/10 min was added to a 90° C. preheatedBrabender Rheometer (C. W. Brabender Instruments, Inc., So. Hackensack,N.J.) equipped with a 50 cc mixing head over 1 minute, while the speedof the mixing blades was set at 8 rpm. The process was shut down afterapproximately ⅓ of the polymer resin had been added since the resin wasnot melting or mixing with resin pellets flying out at the top of theBrabender.

In Example 57, 50 grams of a poly(ethylene-co-methacrylic acid)copolymer containing 19 wt % polymerized residues of methacrylic acidand having a MI of 86 g/10 min was added to a 90° C. preheated BrabenderRheometer equipped with a 50 cc mixing head over 1 minute, while thespeed of the mixing blades was set at 8 rpm. The speed of mixing bladeswas then increased to 30 rpm and the polymer resin was further mixed for5 minutes, after which, a homogeneous polymer melt was achieved with themixing motor at 0.5 amp and the polymer melt temperature at 106° C. Theprocess was shut down.

The results demonstrated that high flow acid copolymers (Example 57) canbe compounded at temperatures low enough (about 90° C.) for theincorporation of organic peroxides through commercially-viable andscalable extrusion compounding equipment while corresponding low flowacid copolymers (Comparative Example CE1) can not.

1-25. (canceled)
 26. A process for manufacturing an article, saidarticle comprising an interlayer and an additional layer selected fromthe group consisting of glass, other polymeric interlayer sheets,polymeric film layers, ceramic plates and metal films or sheets; saidprocess comprising the steps of: providing a composition comprising anon-neutralized acid copolymer of an alpha olefin and about 15 to about23 wt % of an alpha,beta-ethylenically unsaturated carboxylic acidhaving 3 to 8 carbons, based on the total weight of the acid copolymer,wherein the acid copolymer has a Melt Index of greater than 100 to about600 g/10 min, as measured by ASTM D1238 at 190° C. and under a load of2160 g; and about 0.01 to about 10 wt %, based upon the total weight ofthe acid copolymer composition, of one or more organic peroxides;compounding the composition at a temperature of 100° C. or less toprevent premature cross-linking; extruding the composition at atemperature of 100° C. or less to form a polymeric film or sheet; layingup a pre-press assembly comprising the polymeric film or sheet and theadditional layer; forming the article by laminating the pre-pressassembly at a temperature of 115° C. or greater to cure the composition;and optionally, subjecting the pre-press assembly to vacuum, to positivepressure, or to a second heating step at a temperature of 145° C.;wherein the composition of the polymeric film or sheet has cross-linkedto form the interlayer.
 27. The article that is the product of theprocess of claim
 26. 28. The article of claim 27 that is a safety glasslaminate.
 29. The article of claim 27 that is a solar cell module. 30.The process of claim 26, wherein (a) the alpha olefin is ethylene; (b)the alpha,beta-ethylenically unsaturated carboxylic acid is selectedfrom the group consisting of acrylic acid, methacrylic acid, itaconicacid, maleic acid, maleic anhydride, fumaric acid, monomethyl maleicacid, and mixtures thereof; and (c) the acid copolymer has a Melt Indexof greater than 100 to about 400 g/10 min.
 31. The process of claim 26,wherein the acid copolymer comprises about 18 to about 23 wt % of repeatunits derived from the alpha,beta-ethylenically unsaturated carboxylicacid.
 32. The process of claim 26, wherein the acid copolymer comprisesabout 19 to about 22 wt % of repeat units derived from thealpha,beta-ethylenically unsaturated carboxylic acid.
 33. The process ofclaim 26, wherein the acid copolymer further comprises 0 to about 50 wt%, based on the total weight of the acid copolymer, of repeat unitsderived from one or more other unsaturated comonomers selected from thegroup consisting of methyl acrylate, methyl methacrylate, ethylacrylate, ethyl methacrylate, isopropyl acrylate, isopropylmethacrylate, butyl acrylate, and butyl methacrylate.
 34. The process ofclaim 26, wherein the composition comprises about 0.5 to about 3.0 wt %of the one or more organic peroxides, based on the total weight of theacid copolymer composition, and the one or more organic peroxides areselected from the group consisting of2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(tert-betylperoxy)hexane-3, di-tert-butyl peroxide,tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane,dicumyl peroxide, alpha, alpha'-bis(tert-butyl-peroxyisopropyl)benzene,n-butyl-4,4-bis(tert-butylperoxy)valerate,2,2-bis(tert-butylperoxy)butane, 1,1-bis(tert-butyl-peroxy)cyclohexane,1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane, tert-butylperoxybenzoate, and benzoyl peroxide.
 35. The process of claim 26,wherein the composition further comprises one or more initiators or oneor more inhibitors.
 36. The process of claim 26, wherein the compositionfurther comprises about 0.01 to about 5 wt %, based on the total weightof the acid copolymer composition, of one or more silane couplingagents.
 37. The process of claim 35, wherein the composition comprisesabout 0.05 to about 1 wt% of the one or more silane coupling agents,based on the total weight of the acid copolymer composition, and the oneor more silane coupling agents are selected from the group consisting ofgamma-chloropropylmethoxy-silane, vinyltrimethoxysilane,vinyltriethoxysilane, vinyltris(beta-methoxy-ethoxy)silane,gamma-vinylbenzylpropyltrimethoxysilane,N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,gamma-methacryloxypropyltrimethoxy-silane, vinyltriacetoxysilane,gamma-glycidoxypropyltrimethoxysilane,gamma-glycidoxypropyltriethoxysilane,beta-(3,4-epoxycyclohexyl)ethyltrimethoxy-silane, vinyltrichlorosilane,gamma-mercaptopropylmethoxysilane, gamma-aminopropyltriethoxysilane, andN-beta-(aminoethyl)-gamma-aminopropyl-trimethoxysilane.
 38. The processof claim 26, wherein: (a) the polymeric film or sheet has a thickness ofabout 10 to about 250 mils; (b) the alpha olefin is ethylene; (c) thealpha,beta-ethylenically unsaturated carboxylic acid is selected fromthe group consisting of acrylic acid, methacrylic acid, itaconic acid,maleic acid, maleic anhydride, fumaric acid, monomethyl maleic acid, andmixtures thereof; (d) the acid copolymer has a Melt Index of greaterthan 100 to about 400 g/10 min; (e) the acid copolymer comprises about18 to about 23 wt % of repeat units from the alpha,beta-ethylenicallyunsaturated carboxylic acid; and (f) wherein the composition comprisesabout 0.5 to about 3.0 wt % of the organic peroxide, based on the totalweight of the acid copolymer composition, and the organic peroxide isselected from the group consisting of2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(tert-betylperoxy)hexane-3, di-tert-butyl peroxide,tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane,dicumyl peroxide, alpha, alpha'-bis(tert-butyl-peroxyisopropyl)benzene,n-butyl-4,4-bis(tert-butylperoxy)valerate, 2,2-bis(tert-butylperoxy)butane, 1,1-bis(tert-butyl-peroxy)cyclohexane,1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane, tert-butylperoxybenzoate, benzoyl peroxide and mixtures thereof; and, optionally(g) about 0.01 to about 5 wt %, based on the total weight of the acidcopolymer composition, of one or more silane coupling agents selectedfrom the group consisting of gamma-chloropropylmethoxy-silane,vinyltrimethoxysilane, vinyltriethoxysilane,vinyltris(beta-methoxy-ethoxy)silane,gamma-vinylbenzylpropyltrimethoxysilane,N-beta-(N-vinylbenzylaminoethyl)-gamma-aminopropyltrimethoxysilane,gamma-methacryloxypropyltrimethoxy-silane, vinyltriacetoxysilane,gamma-glycidoxypropyltrimethoxysilane,gamma-glycidoxypropyltriethoxysilane,beta-(3,4-epoxycyclohexyl)ethyltrimethoxy-silane, vinyltrichlorosilane,gamma-mercaptopropylmethoxysilane, gamma-aminopropyltriethoxysilane, andN-beta-(aminoethyl)-gamma-aminopropyl-trimethoxysilane.
 39. The processof claim 26, wherein the polymeric film or sheet is a multilayer film orsheet comprising two or more sub-layers, wherein at least one of thesub-layers comprises the composition, and wherein the other sub-layer(s)comprise a polymer selected from the group consisting of acid copolymersand ionomers derived therefrom, poly(ethylene vinyl acetate), poly(vinylacetal), polyurethane, polyvinylchloride, polyethylenes, polyolefinblock elastomers, ethylene acrylate ester copolymers, siliconeelastomers and epoxy resins.
 40. The process of claim 26, wherein thepolymeric film or sheet is treated to enhance the adhesion to otherlaminate layers.
 41. The process of claim 40, wherein the treatmentcomprises applying a monolayer of an adhesive/primer coating to thepolymeric film or sheet.
 42. The process of claim 26, wherein theadditional layer is a rigid sheet selected from the group consisting ofwindow glass, plate glass, silicate glass, sheet glass, low iron glass,tempered glass, tempered CeO-free glass, float glass, colored glass,specialty glass, coated glass, E-glass, Toroglass, Solex® glass,polycarbonate, acrylics, polyacrylate, cyclic polyolefins,metallocene-catalyzed polystyrene, polyamides, polyesters,fluoropolymers, metal sheets and ceramic plates.
 43. The process ofclaim 26, wherein the additional layer is an other polymeric interlayersheet selected from the group consisting of acid copolymers and ionomersderived therefrom, poly(ethylene vinyl acetate), poly(vinyl acetal),polyurethane, polyvinylchloride, polyethylenes, polyolefin blockelastomers, ethylene acrylate ester copolymers, silicone elastomers andepoxy resins.
 44. The process of claim 26, wherein the additional layeris a polymeric film layer selected from the group consisting of metalfoils, limited to, polyesters, poly(ethylene naphthalate),polycarbonate, polyolefins, norbornene polymers, polystyrene,styrene-acrylate copolymers, acrylonitrile-styrene copolymers,polysulfones, nylons, poly(urethanes), acrylics, cellulose acetates,cellophane, vinyl chloride polymers, and fluoropolymers.
 45. The processof claim 26, wherein the pre-press assembly comprises layers in an orderselected from the group consisting of a glass layer/the polymeric filmor sheet; a glass layer/the polymeric film or sheet/a second glasslayer; a glass layer/the polymeric film or sheet/the polymeric filmlayer; a glass layer/the polymeric film or sheet/the polymeric filmlayer/a second polymeric film or sheet/a second glass layer; and a glasslayer/the polymeric film or sheet/the polymeric film layer/a secondpolymeric film or sheet/a second polymeric film layer.